Metals in a sense are chemicals because they are produced by chemical means, the ores sometimes requiring chemical methods of dressing before refining; the refining process also involves chemical reactions. Such metals as steel, lead, copper, and zinc are produced in reasonably pure form and are later fabricated into useful shapes. Yet the steel industry, for example, is not considered a part of the chemical industry. In modern metallurgy, such metals as titanium, tantalum, and tungsten are produced by processes involving great chemical skill, yet they are still classified as primary metals.

The boundaries of the chemical industry, then, are somewhat confused. Its main raw materials are the fossil fuels (coal, natural gas, and petroleum), air, water, salt, limestone, sulfur or an equivalent, and some specialized raw materials for special products, such as phosphates and the mineral fluorspar. The chemical industry converts these raw materials into primary, secondary, and tertiary products, a distinction based on the remoteness of the product from the consumer, the primary being remotest. The products are most often end products only as regards the chemical industry itself; a chief characteristic of the chemical industry is that its products nearly always require further processing before reaching the ultimate consumer.
Statistics from the chemical industry as a whole can be misleading because of the practice of lumping together such products as inexpensive sulfuric acid and expensive dyes or fibres; included in some compilations are cosmetics and toiletries, the value of which per pound may be artificially high. Chemical industry statistics from different countries may have different bases of calculation; indeed the basis may change from time to time in the same country. An additional source of confusion is that in some cases the production is quoted not in tons of the product itself but in tons of the content of the important component.

For purposes of simplicity, various divisions of the chemical industry, such as heavy inorganic and organic chemicals and various families of end products, will be described in turn and separately, although it should be borne in mind that they interact constantly. The first division to be discussed is the heavy inorganic chemicals, starting at the historical beginning of the chemical industry with the Leblanc process. The terms heavy chemical industry and light chemical industry, however, are not precisely exclusive, because numerous operations fall somewhere between the two classes. The two classes do, however, at their extremes correlate with other differences. For example, the appearance of two kinds of plants is characteristically different. The large-scale chemical plant is characterized by large pieces of equipment of odd shapes and sizes standing immobile and independent of one another. Long rows of distilling columns are prominent, but, because the material being processed is normally confined in pipes or vessels, no very discernible activity takes place. Few personnel are in evidence.